• 2-Butene-1,4-diol

2-Butene-1,4-diol

  • CasNo：110-64-5
  • Purity：99%

Product Details;

CasNo： 110-64-5

Molecular Formula： C4H8O2

Appearance： clear to pale yellow liquid

Factory Supply 110-64-5 110-63-4 Cheap Price

  • Molecular Formula:C4H8O2
  • Molecular Weight:88.1063
  • Appearance/Colour:clear to pale yellow liquid 
  • Vapor Pressure:2.46E-07mmHg at 25°C 
  • Melting Point:4-10 °C(lit.) 
  • Refractive Index:FLASH POINT 
  • Boiling Point:235 °C at 760 mmHg 
  • PKA:14.17±0.10(Predicted) 
  • Flash Point:85.4 °C 
  • PSA：40.46000 
  • Density:1.059 g/cm3 
  • LogP:-0.47280 

2-Butene-1,4-diol(Cas 110-64-5) Usage

Reactivity Profile

2-Butene-1,4-diol forms furan (narcotic)when treated with dichromate in acidic solution.Dehydration of the cis-isomer overacid catalysts yields 2,5-dihydrofuran (narcotic).Halogens form substitution or additionproducts, 4-halobutenols, or 2,3-dihalo-1,4-butanediol. These are toxic compounds.Ammonia or amine form pyrroline or itsderivatives (moderately toxic).

Health Hazard

2-Butene-1,4-diol is a depressant of the Centralnervous system. Inhalation toxicity isvery low due to its low vapor pressure. Theoral LD50 value in rats and guinea pigs is1.25 mL/kg. It is a primary skin irritant.

Fire Hazard

Noncombustible liquid; flash point (open cup) 128°C.

InChI:InChI=1/2C4H8O2/c2*5-3-1-2-4-6/h2*1-2,5-6H,3-4H2/b2-1+;2-1-

110-64-5 Relevant articles

Towards Sustainable Catalysis – Highly Efficient Olefin Metathesis in Protic Media Using Phase Labelled Cyclic Alkyl Amino Carbene (CAAC) Ruthenium Catalysts

Nagyházi, Márton,Turczel, Gábor,Balla, áron,Szálas, Gábor,Tóth, Imre,Gál, Gyula Tamás,Petra, Bombicz,Anastas, Paul T.,Tuba, Róbert

, p. 1953 - 1957 (2020)

New generations of Hoveyda and bis-carbe...

Ultra-Small Platinum Nanoparticles with High Catalytic Selectivity Synthesized by an Eco-friendly Method Supported on Natural Hydroxyapatite

Gama-Lara,Natividad,Vilchis-Nestor,López-Casta?ares, Rafael,García-Orozco,Gonzalez-Pedroza, María G.,Morales-Luckie, Raúl A.

, p. 3447 - 3453 (2019)

Abstract: The biosynthesis of Pt-nanopar...

Continuous flow olefin metathesis using a multijet oscillating disk reactor as the reaction platform

Bjorsvik, Hans-Ren,Liguori, Lucia

, p. 1509 - 1515 (2014)

The multijet oscillating disk (MJOD) flo...

Ammonium-tagged ruthenium-based catalysts for olefin metathesis in aqueous media under ultrasound and microwave irradiation

Gu?ajski, ?ukasz,Tracz, Andrzej,Urbaniak, Katarzyna,Czarnocki, Stefan J.,Bieniek, Micha?,Olszewski, Tomasz K.

, p. 160 - 166 (2019)

The influence of microwave and ultrasoni...

A solid-supported phosphine-free ruthenium alkylidene for olefin metathesis in methanol and water.

Connon, Stephen J,Blechert, Siegfried

, p. 1873 - 1876 (2002)

The synthesis and olefin metathesis acti...

Photovoltaic-driven organic electrosynthesis and efforts toward more sustainable oxidation reactions

Nguyen, Bichlien H.,Perkins, Robert J.,Smith, Jake A.,Moeller, Kevin D.

, p. 280 - 287 (2015)

The combination of visible light, photov...

The influence of nickel loading on the structure and performance of a Ni-Al2O3 catalyst for the hydrogenation of 1,4-butynediol to produce 1,4-butenediol

Gao, Xianlong,Mo, Wenlong,Ma, Fengyun,Fan, Xing

, p. 7683 - 7689 (2020)

In combination with a planetary ball-mil...

The stereochemistry of solvolysis of an acyclic allylic epoxide

Boaz

, p. 15 - 16 (1995)

In contrast to solvolysis of cyclic ally...

Sunlight, electrochemistry, and sustainable oxidation reactions

Nguyen, Bichlien H.,Redden, Alison,Moeller, Kevin D.

, p. 69 - 72 (2014)

Inexpensive, readily available photovolt...

Highly selective semi-hydrogenation of alkynes with a Pd nanocatalyst modified with sulfide-based solid-phase ligands

Huang, Lingqi,Hu, Kecheng,Ye, Ganggang,Ye, Zhibin

, (2021)

Soluble small molecular/polymeric ligand...

A simple and practical preparation of an efficient water soluble olefin metathesis catalyst

Wang, Zhen J.,Jackson, W. Roy,Robinson, Andrea J.

, p. 3407 - 3414 (2015)

This study details homogeneous olefin me...

Highly Efficient Catalytic Formation of (Z)-1,4-But-2-ene Diols Using Water as a Nucleophile

Guo, Wusheng,Martínez-Rodríguez, Luis,Martin, Eddy,Escudero-Adán, Eduardo C.,Kleij, Arjan W.

, p. 11037 - 11040 (2016)

The first general catalytic and highly s...

Synthesis of diols from 1,2-epoxy-3-butene

Mel'nik,Srednev,Rybina,Meshechkina,Shevchuk,Danilova

, p. 201 - 204 (2007)

The catalytic hydration of 1,2-epoxy-3-b...

Dehydrogenative alcohol coupling and one-pot cross metathesis/dehydrogenative coupling reactions of alcohols using Hoveyda-Grubbs catalysts

?zer, Halenur,Arslan, Dilan,?ztürk, Bengi ?zgün

, p. 5992 - 6000 (2021/04/12)

In this study,in situformed ruthenium hy...

Preparation method of N-(4-methylpyridine-3-yl) methyl carbamate

-

Paragraph 0020; 0022; 0025; 0030; 0032; 0035; 0040; 0042, (2021/06/02)

The invention relates to the technical f...

Continuous Flow Z-Stereoselective Olefin Metathesis: Development and Applications in the Synthesis of Pheromones and Macrocyclic Odorant Molecules**

Browne, Duncan L.,Colombel-Rouen, Sophie,Crévisy, Christophe,Curbet, Idriss,Mauduit, Marc,McBride, Tom,Morvan, Jennifer,Roisnel, Thierry

supporting information, p. 19685 - 19690 (2021/08/06)

The first continuous flow Z-selective ol...

110-64-5 Process route

1,4-dihydroxybut-2-yne
110-65-6

1,4-dihydroxybut-2-yne

Butane-1,4-diol
110-63-4

Butane-1,4-diol

(E/Z)-2-buten-1-ol
6117-91-5,542-72-3

(E/Z)-2-buten-1-ol

1,4-butenediol
821-11-4,6117-80-2,110-64-5

1,4-butenediol

Conditions
Conditions Yield
With hydrogen; In water; at 22 ℃; under 760.051 Torr; chemoselective reaction;
 
buta-1,3-diene
106-99-0,130983-70-9,29406-96-0,9003-17-2

buta-1,3-diene

epoxybutene
930-22-3,62249-81-4

epoxybutene

furan
110-00-9

furan

3,4-butenediol
497-06-3,86161-40-2

3,4-butenediol

1,4-butenediol
821-11-4,6117-80-2,110-64-5

1,4-butenediol

acrolein
107-02-8,25068-14-8

acrolein

Conditions
Conditions Yield
With 5C6H11N2(1+)*Na(1+)*O39PW11(7-)*H(1+); dihydrogen peroxide; In water; acetonitrile; at 50 ℃; for 5h; Reagent/catalyst; Gas phase;
1540 mmol
68 mmol
10 mmol
8 mmol
5 mmol

110-64-5 Upstream products

  • 6974-12-5
    6974-12-5

    1,4-dibromo-2-butene

  • 930-22-3
    930-22-3

    epoxybutene

  • 764-41-0
    764-41-0

    1,4-dichloro-2-butene

  • 87-69-4
    87-69-4

    L-Tartaric acid

110-64-5 Downstream products

  • 19311-38-7
    19311-38-7

    3-chlorotetrahydrofuran

  • 1708-29-8
    1708-29-8

    2,5-dihydrofuran

  • 21485-51-8
    21485-51-8

    2,5-Divinyl-[1,4]dioxan

  • 20163-90-0
    20163-90-0

    2,3-dibromo-1,4-dihydroxy-2-butane

Inquiry

Name:
*CompanyName:
*Email:
*Requirements:
*Code:
Submit