• 1,4-Butanediol

1,4-Butanediol

  • CasNo：110-63-4
  • Purity：99%

Product Details;

CasNo： 110-63-4

Molecular Formula： C4H10O2

Appearance： viscous colourless liquid

Manufacturer Supply Wholesale 110-63-4 price in stock

  • Molecular Formula:C4H10O2
  • Molecular Weight:90.1222
  • Appearance/Colour:viscous colourless liquid 
  • Vapor Pressure:0.015mmHg at 25°C 
  • Melting Point:20 °C 
  • Refractive Index:n20/D 1.445(lit.)  
  • Boiling Point:227.999 °C at 760 mmHg 
  • PKA:14.73±0.10(Predicted) 
  • Flash Point:105.909 °C 
  • PSA：40.46000 
  • Density:1.006 g/cm3 
  • LogP:-0.24880 

1,4-Butanediol(Cas 110-63-4) Usage

InChI:InChI=1/C4H10O2/c5-3-1-2-4-6/h5-6H,1-4H2

110-63-4 Relevant articles

Effect of boron content on 1,4-butanediol production by hydrogenation of succinic acid over Re-Ru/BMC (boron-modified mesoporous carbon) catalysts

Kang, Ki Hyuk,Han, Seung Ju,Lee, Jong Won,Kim, Tae Hyeop,Song, In Kyu

, p. 206 - 213 (2016)

A series of Re-Ru bimetallic catalysts s...

Hydrogenation of γ-Butyrolactone to 1,4-Butanediol over CuCo/TiO2 Bimetallic Catalysts

Huang, Zhiwei,Barnett, Kevin J.,Chada, Joseph P.,Brentzel, Zachary J.,Xu, Zhuoran,Dumesic, James A.,Huber, George W.

, p. 8429 - 8440 (2017)

Titania-supported monometallic and bimet...

Extremely facile and selective nickel-catalyzed allyl ether cleavage

Taniguchi, Takahiko,Ogasawara, Kunio

, p. 1136 - 1137 (1998)

Child's play! Allyl ethers as protecting...

Thermodynamic equilibria between polyalcohols and cyclic ethers in high-temperature liquid water

Yamaguchi, Aritomo,Hiyoshi, Norihito,Sato, Osamu,Bando, Kyoko K.,Masuda, Yoshio,Shirai, Masayuki

, p. 2666 - 2668 (2009)

Thermodynamic equilibrium constants betw...

-

Enz,W.

, p. 206 - 212 (1961)

-

A temperature-controlled reversible ionic liquid - Water two phase - Single phase protocol for hydrogenation catalysis

Dyson,Ellis,Welton

, p. 705 - 708 (2001)

An ionic liquid - water system that unde...

Comparison of Carbon-13 Nuclear Magnetic Resonance Methods for the Analysis of Multiple Partially Deuteriated Products from Catalytic Reactions: Heptan-1-ol and 2-Methylpropanol

MacDougall, Joanna K.,Simpson, Michael C.,Cole-Hamilton, David J.

, p. 3061 - 3066 (1994)

Products from the hydrocarbonylation of ...

A Study of the Catalytic Deuteration of 1,4-Butynediol

Chickos, James S.,Uang, Jack Y.-J.,Keiderling, Tim A.

, p. 2594 - 2596 (1991)

-

High chemo and regioselective formation of alcohols from the hydrocarbonylation of alkenes using cooperative ligand effects

Boogaerts, Ine T.I. F.,White, Daniel F. S.,Cole-Hamilton, David J.

, p. 2194 - 2196 (2010)

The hydrocarbonylation of alkenes, inclu...

Continuous hydrogenation of 2-butyne-1,4-diol to 2-butene- and butane-1,4-diols

Rode,Tayade,Nadgeri,Jaganathan,Chaudhari

, p. 278 - 284 (2006)

Continuous catalytic hydrogenation of 2-...

A new carboxylesterase from Brevibacterium linens IFO 12171 responsible for the conversion of 1,4-butanediol diacrylate to 4-hydroxybutyl acrylate: Purification, characterization, gene cloning, and gene expression in Escherichia coli

Sakai, Yasuyoshi,Ishikawa, Junko,Fukasaka, Shunji,Yurimoto, Hiroya,Mitsui, Ryoji,Yanase, Hideshi,Kato, Nobuo

, p. 688 - 697 (1999)

A carboxylesterase that is responsible f...

Effect of Ethers on Reactions of Butylcoppers with α,β-Unsaturated Ketones in Toluene

Kingsbury, Celia L.,Smith, Robin A. J.

, p. 7637 - 7643 (1997)

Mixtures of butyllithium and copper iodi...

A Novel and Unusual Reaction of Enol Ethers with Benzyltriethylammonium Borohydride and Chlorotrimethylsilane

Baskaran, S.,Chidambaram, N.,Narasimhan, N.,Chandrasekaran, S.

, p. 6371 - 6374 (1992)

Benzyltriethylammonium borohydride-chlor...

A Schiff Base Modified Pd Catalyst for Selective Hydrogenation of 2-Butyne-1,4-diol to 2-Butene-1,4-diol

Li, Haomeng,Wang, Xinkui,Chen, Xiao,Li, Chuang,Wang, Min,Yi, Yanhui,Ji, Min,Wang, Huilong,Shao, Zhengfeng,Liang, Changhai

, p. 2150 - 2157 (2020)

Abstract: Schiff-base modified Pd nanopa...

Bimetallic Synergy Effects of Phyllosilicate-Derived NiCu@SiO2 Catalysts for 1,4-Butynediol Direct Hydrogenation to 1,4-Butanediol

Wang, Changzhen,Tian, Yani,Wu, Ruifang,Li, Haitao,Yao, Benzhen,Zhao, Yongxiang,Xiao, Tiancun

, p. 4777 - 4787 (2019)

Hydrogenation of 1,4-butynediol (BYD) to...

Quantification of Interfacial pH Variation at Molecular Length Scales Using a Concurrent Non-Faradaic Reaction

Ryu, Jaeyune,Wuttig, Anna,Surendranath, Yogesh

, p. 9300 - 9304 (2018)

We quantified changes in interfacial pH ...

Modelling proposed intermediates in the hydrocarbonylation of alkenes catalysed by rhodium complexes of PBui3 and PPr i3

Cheliatsidou, Paraskevi,White, Daniel F. S.,Slawin, Alexandra M. Z.,Cole-Hamilton, David J.

, p. 2389 - 2394 (2008)

In ethanol, hydrocarbonylation reactions...

DIRECT SYNTHESIS OF 1,4-BUTANEDIOL FROM ALLYL ALCOHOL USING CARBON MONOXIDE AND WATER IN THE PRESENCE OF Rh6(CO)16-PROPANEDIAMINE SYSTEM

Kaneda, Kiyotomi,Imanaka, Toshinobu,Teranishi, Shiichiro

, p. 1465 - 1466 (1983)

Rh6(CO)16-propanediamine system catalyze...

An unusual reaction of cyclic enol ethers with titanium(III) tetrahydroborate

Ravikumar,Chandrasekaran, Srinivasan

, p. 2973 - 2978 (1997)

Titanium(III) Tetrahydroborate formed in...

Alkaline hydrolysis of oligomers of tartrate esters: Effect of a neighboring carboxyl on the reactivity of ester groups

Maniar,Kalonia,Simonelli

, p. 705 - 709 (1992)

The importance and the effect of neighbo...

New environmentally friendly catalysts containing Pd-interstitial carbon made from Pd-glucose precursors for ultraselective hydrogenations in the liquid phase

Chan, Chun Wong Aaron,Xie, Yaling,Cailuo, Nick,Yu, Kai Man Kerry,Cookson, James,Bishop, Peter,Tsang, Shik Chi

, p. 7971 - 7973 (2011)

We report a novel preparation of a Pd na...

Zirconium(IV) chloride catalyzed new and efficient protocol for the selective cleavage of p-methoxybenzyl ethers

Madhava Sharma, Gangavaram V.,Reddy, Ch. Govardhan,Krishna, Palakodety Radha

, p. 4574 - 4575 (2003)

A highly selective and efficient method ...

Efficient Pd@MIL-101(Cr) hetero-catalysts for 2-butyne-1,4-diol hydrogenation exhibiting high selectivity

Yin, Dongdong,Li, Chuang,Ren, Hangxing,Shekhah, Osama,Liu, Jinxuan,Liang, Changhai

, p. 1626 - 1633 (2017)

Pd@MIL-101(Cr) hetero-catalysts have bee...

Aqueous phase hydrogenation of acetic acid to ethanol over Ir-MoO x/SiO2 catalyst

Wang, Zhiqiang,Li, Guangyi,Liu, Xiaoyan,Huang, Yanqiang,Wang, Aiqin,Chu, Wei,Wang, Xiaodong,Li, Ning

, p. 38 - 41 (2014)

Mo modified Ir/SiO2 (Ir-MoOx/SiO2) was f...

Biosynthesis of 1,4-butanediol from erythritol using whole-cell catalysis

Dai, Lu,Tai, Cui,Shen, Yaling,Guo, Yali,Tao, Fei

, p. 1 - 5 (2018)

1,4-Butanediol (BDO) biosynthesis from r...

Raney Ni-Si catalysts for selective hydrogenation of highly concentrated 2-butyne-1,4-diol to 2-butene-1,4-diol

Chen, Xiao,Zhang, Mingming,Yang, Kaixuan,Williams, Christopher T.,Liang, Changhai

, p. 1118 - 1126 (2014)

Raney Ni-Si catalysts were synthesized b...

Kinetics and mechanism of tetrahydrofuran synthesis via 1,4-butanediol dehydration in high-temperature water

Hunter, Shawn E.,Ehrenberger, Carolyn E.,Savage, Phillip E.

, p. 6229 - 6239 (2006)

We conducted an experimental investigati...

Highly dispersed palladium nanoclusters incorporated in amino-functionalized silica spheres for the selective hydrogenation of succinic acid to γ-butyrolactone

You, Chenjia,Zhang, Chi,Chen, Lifang,Qi, Zhiwen

, p. 653 - 660 (2015)

Highly dispersed palladium nanoclusters ...

Liquid-phase catalytic hydrogenation of 2-butyne-1,4-diol to 1,4-butanediol at atmospheric pressure on suspended catalysts

Pyatnitsyna,El'Chaninov

, p. 394 - 397 (2013)

The optimum parameters of hydrogenation ...

Analysis of drugs by pyrolysis. I. Selected ion monitoring combined with a pyrolysis method for the determination of carpronium chloride in biological samples.

Ohya,Sano

, p. 241 - 247 (1977)

In order to establish an analytical meth...

Hot Water Induces an Acid-Catalyzed Reaction in Its Undissociated Form

Nagai, Yasuharu,Matubayasi, Nobuyuki,Nakahara, Masaru

, p. 691 - 697 (2004)

Hot water in its undissociated form has ...

Selective Hydrogenation of Cyclic Ester to α,ω-Diol Catalyzed by Cationic Ruthenium Complexes with Trialkylphosphine Ligands

Hara, Yoshinori,Inagaki, Hiroko,Nishimura, Sugio,Wada, Keisuke

, p. 1983 - 1986 (1992)

Cyclic esters like γ-butyrolactone were ...

Pt nanoparticles over TiO2-ZrO2 mixed oxide as multifunctional catalysts for an integrated conversion of furfural to 1,4-butanediol

Li, Fengbo,Lu, Tao,Chen, Bingfeng,Huang, Zhijun,Yuan, Guoqing

, p. 252 - 258 (2014)

1,4-butanediol (BDO) is an important com...

Tracking Electrical Fields at the Pt/H2O Interface during Hydrogen Catalysis

Ryu, Jaeyune,Surendranath, Yogesh

, p. AR (2019)

We quantify changes in the magnitude of ...

First example of borirane synthesis by α-olefins reaction with BCl3·SMe2 Catalyzed with (η5-C5H5)2TiCl2

Khusainova,Khafizova,Tyumkina,Dzhemilev

, p. 1517 - 1523 (2015)

New method was developed of the synthesi...

Converging conversion - using promiscuous biocatalysts for the cell-free synthesis of chemicals from heterogeneous biomass

Pick, André,Sieber, Volker,Sutiono, Samuel

, p. 3656 - 3663 (2021)

Production of chemicals from lignocellul...

Reductive cleavage of tert-butyldimethylsilyl ether via intramolecular transfer of hydride

Saravanan, Parthasarathy,Gupta, Suparna,DattaGupta, Arpita,Gupta, Sonia,Singh, Vinod K.

, p. 2695 - 2699 (1997)

The cleavage of α-hydroxy tert-butyldime...

Catalytic hydrogenation of 2-butyne-1,4-diol to 2-butene-1,4-diol at atmospheric pressure in the liquid phase

Pyatnitsyna,El'chaninov,Savost'yanov

, p. 89 - 92 (2006)

Selective hydrogenation of 2-butyne-1,4-...

A synthesis method of diol

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Paragraph 0043-0048, (2022/01/12)

The present invention belongs to the fie...

Method for producing a shaped catalyst body

-

Page/Page column 29-30, (2021/11/19)

Provided herein is a novel process for p...

Hydroboration Reaction and Mechanism of Carboxylic Acids using NaNH2(BH3)2, a Hydroboration Reagent with Reducing Capability between NaBH4and LiAlH4

Wang, Jin,Ju, Ming-Yue,Wang, Xinghua,Ma, Yan-Na,Wei, Donghui,Chen, Xuenian

, p. 5305 - 5316 (2021/04/12)

Hydroboration reactions of carboxylic ac...

110-63-4 Process route

C<sub>36</sub>H<sub>60</sub>O<sub>30</sub>*C<sub>4</sub>H<sub>10</sub>O<sub>2</sub>

C36H60O30*C4H10O2

Butane-1,4-diol
110-63-4

Butane-1,4-diol

alpha cyclodextrin
10016-20-3

alpha cyclodextrin

Conditions
Conditions Yield
In water; at 25 ℃; Equilibrium constant;
dimethyl cis-but-2-ene-1,4-dioate
624-48-6

dimethyl cis-but-2-ene-1,4-dioate

tetrahydrofuran
109-99-9,24979-97-3,77392-70-2

tetrahydrofuran

2-methoxytetrahydrofuran
13436-45-8

2-methoxytetrahydrofuran

4-butanolide
96-48-0

4-butanolide

propan-1-ol
71-23-8

propan-1-ol

1-methoxy-1,4-butanediol

1-methoxy-1,4-butanediol

2-(4'-hydroxybutoxy)-tetrahydrofuran
64001-06-5

2-(4'-hydroxybutoxy)-tetrahydrofuran

4-hydroxy-butanoic acid 4-hydroxybutyl ester

4-hydroxy-butanoic acid 4-hydroxybutyl ester

Butane-1,4-diol
110-63-4

Butane-1,4-diol

4-hydroxybutyraldehyde
25714-71-0

4-hydroxybutyraldehyde

methyl 4-hydroxybutanoate
925-57-5

methyl 4-hydroxybutanoate

butan-1-ol
71-36-3

butan-1-ol

Conditions
Conditions Yield
With hydrogen; at 190 ℃; under 46504.7 Torr; Gas phase;
79.1%
10.4%
5.3%

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