• N-(1-Methylethyl)-benzenemethanamine

N-(1-Methylethyl)-benzenemethanamine

  • CasNo：102-97-6
  • Purity：99%

Product Details;

CasNo： 102-97-6

Molecular Formula： C10H15N

Appearance： Clear, very slightly yellow to yellow liquid

Top Purity 99% 102-97-6 with Low Price and Safe Transportation

  • Molecular Formula:C10H15N
  • Molecular Weight:149.236
  • Appearance/Colour:Clear, very slightly yellow to yellow liquid 
  • Vapor Pressure:0.332mmHg at 25°C 
  • Melting Point:143°C (estimate) 
  • Refractive Index:n20/D 1.502(lit.)  
  • Boiling Point:199.999 °C at 760 mmHg 
  • PKA:9.77±0.19(Predicted) 
  • Flash Point:87.778 °C 
  • PSA：12.03000 
  • Density:0.907 g/cm3 
  • LogP:2.57550 

N-(1-Methylethyl)-benzenemethanamine(Cas 102-97-6) Usage

Preparation

N-benzylisopropylamine is synthesized by the reduction reaction of N-isopropylbenzamide or prepared from benzylamine and acetone by reductive amination reaction.

Application

N-Isopropylbenzylamine was used as ligand in the preparation and characterization of bis(cyclopentadienyl)magnesium. It was also used in the synthesis of N-benzylideneisopropylamine-N-oxide.

General Description

N-isopropylbenzylamine is a structural isomer of methamphetamine, is one of the most common adulterants. It forms amine adducts with magnesocene at ambient temperature in toluene.

InChI:InChI=1/C10H15N/c1-9(2)11-8-10-6-4-3-5-7-10/h3-7,9,11H,8H2,1-2H3/p+1

102-97-6 Relevant articles

Selective hydrogenation of nitriles to secondary amines catalyzed by a pyridyl-functionalized and alkenyl-tethered NHC-Ru(II) complex

Saha, Sayantani,Kaur, Mandeep,Singh, Kuldeep,Bera, Jitendra K.

, p. 87 - 94 (2016)

A set of Co(III) and Ru(II) compounds ar...

Stereoselective pinacol coupling of planar chiral (benzaldehyde)Cr(Co)3, (benzaldimine)Cr(CO)3, ferrocenecarboxaldehyde and (dienal)Fe(CO)3 complexes with samarium diiodide

Taniguchi, Nobukazu,Uemura, Motokazu

, p. 12775 - 12788 (1998)

An intermolecular pinacol coupling of th...

Design of a bifunctional Ir-Zr based metal-organic framework heterogeneous catalyst for the N-alkylation of amines with alcohols

Rasero-Almansa,Corma,Iglesias,Sanchez

, p. 1794 - 1800 (2014)

The direct N-alkylation of amines with a...

First example of direct reductive amination of aldehydes with primary and secondary amines catalyzed by water-soluble transition metal catalysts

Robichaud, André,Nait Ajjou, Abdelaziz

, p. 3633 - 3636 (2006)

An unprecedented efficient and highly se...

Stereodynamics of 2-(diethylamino)propane and 2-(dibenzylamino)propane. 1H and 13C{1H} DNMR studies. Molecular mechanics calculations

Brown, Jay H.,Bushweller, C. Hackett

, p. 12567 - 12577 (1995)

2-(Diethylamino)propane (DEAP) and 2-(di...

Expanding Water/Base Tolerant Frustrated Lewis Pair Chemistry to Alkylamines Enables Broad Scope Reductive Aminations

Fasano, Valerio,Ingleson, Michael J.

, p. 2217 - 2224 (2017)

Lower Lewis acidity boranes demonstrate ...

Additive-free selective methylation of secondary amines with formic acid over a Pd/In2O3 catalyst

Benaissa, Idir,Cantat, Thibault,Genre, Caroline,Godou, Timothé,Pinault, Mathieu

, p. 57 - 61 (2022/01/19)

Formic acid is used as the sole carbon a...

Hydrogenation of Secondary Amides using Phosphane Oxide and Frustrated Lewis Pair Catalysis

K?ring, Laura,Sitte, Nikolai A.,Bursch, Markus,Grimme, Stefan,Paradies, Jan

supporting information, p. 14179 - 14183 (2021/09/03)

The metal-free catalytic hydrogenation o...

Reductive amination of ketones/aldehydes with amines using BH3N(C2H5)3as a reductant

Zou, Qizhuang,Liu, Fei,Zhao, Tianxiang,Hu, Xingbang

supporting information, p. 8588 - 8591 (2021/09/04)

Herein, we report the first example of e...

Imine reduction with me2s-bh3

Kamal, Mohammad M.,Liu, Zhizhou,Vidovi?, Dragoslav,Zhai, Siyuan

, (2021/09/13)

Although there exists a variety of diffe...

102-97-6 Process route

N-isopropylbenzamide
5440-69-7

N-isopropylbenzamide

N-benzylideneisopropylamine
6852-56-8

N-benzylideneisopropylamine

Benzyl-isopropyl-amin
102-97-6

Benzyl-isopropyl-amin

Conditions
Conditions Yield
With diphenylsilane; tris(triphenylphosphine)rhodium(I) chloride; In tetrahydrofuran; at 50 ℃; for 6h;
5 % Spectr.
52 % Spectr.
formic acid
64-18-6

formic acid

benzylamine
100-46-9

benzylamine

N,N'-dimethylbenzylamine
103-83-3

N,N'-dimethylbenzylamine

N-methyl-N-benzylformamide
17105-71-4

N-methyl-N-benzylformamide

N-benzylformamide
6343-54-0

N-benzylformamide

N,N-diethylbenzylamine
772-54-3

N,N-diethylbenzylamine

Benzyl-isopropyl-amin
102-97-6

Benzyl-isopropyl-amin

N-benzyl-N-formylformamide
55756-18-8

N-benzyl-N-formylformamide

Conditions
Conditions Yield
With indium oxide nanoparticles decorated with palladium oxide; In 1,2-dimethoxyethane; at 200 ℃; for 18h;
40%

102-97-6 Upstream products

  • 100-39-0
    100-39-0

    benzyl bromide

  • 75-31-0
    75-31-0

    isopropylamine

  • 72846-70-9
    72846-70-9

    isopropyl phenyl ketoxime

  • 100-44-7
    100-44-7

    benzyl chloride

102-97-6 Downstream products

  • 87040-39-9
    87040-39-9

    (+/-)-benzylisopropyl(α-hydroxyphenethyl)amine

  • 27171-30-8
    27171-30-8

    N-benzyl-N-isopropyl-2,3-epoxypropylamine

  • 20278-21-1
    20278-21-1

    N-Benzyl-N-isopropylformamid (anti)

  • 60882-81-7
    60882-81-7

    N-2-Propyl-N-benzyl-2,4,6-trinitrobenzolsulfenamid

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